Cisco Switching/Routing :: 3750 How To Write Access List

i have one Cisco 3750, am using it as Core Switch where i have 6 more access switches are connected deirectly, and we are using VLANs in our network with the IP reange of 172.16.0.0 , now we had a new Internet connection which is dedicated to Exchange Server only.So we have TWO internet connection One for internet access to all users and another one for only Exchange Server.internet connection for the users is termiated at a Cisco 1700 Series Router and Internet for Exchage Server is terminated at a Cisco ASA Firewall.Now the problem is how can i write an access list, which says that all packets from Exchange server should be routed to ASA Firewall , and all other packets shoulde route to Cisco Router.IP address os Exchange server is 172.16.2.1, 172.16.2.2.